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Pure Appl. Chem., 2009, Vol. 81, No. 11, pp. 2025-2033

http://dx.doi.org/10.1351/PAC-CON-08-12-04

Published online 2009-10-29

Immobilization of 5,10,15,20-tetrakis-(2-fluorophenyl)porphyrin into MCM-41 and NaY: Routes toward photodegradation of pesticides

Monica Silva1, Maria E. Azenha1*, Mariette M. Pereira1, Hugh D. Burrows1, Mohamed Sarakha2, Maria F. Ribeiro3, Auguste Fernandes3, Paula Monsanto4 and Fernando Castanheira4

1 Department of Chemistry, Faculty of Sciences and Technology, Coimbra University, Rua Larga, 3004-535 Coimbra, Portugal
2 Laboratoire de Photochimie Moléculaire et Macromoléculaire, Université Blaise Pascal, 24, Avenue des Landais, 63177 Aubière, France
3 IBB, Department of Chemical Engineering, IST, Lisbon Technical University, Av. Rovisco Pais, 1049-001 Lisbon, Portugal
4 National Institute of Legal Medicine, Centre Branch, Department of Forensic Toxicology, Largo da Sé Nova, 3000-213 Coimbra, Portugal

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  • Calvete Mário J. F., Silva Mónica, Pereira Mariette M., Burrows Hugh D.: Inorganic helping organic: recent advances in catalytic heterogeneous oxidations by immobilised tetrapyrrolic macrocycles in micro and mesoporous supports. RSC Adv. 2013, 3, 22774. <http://dx.doi.org/10.1039/c3ra44038a>
  • Silva M., Calvete M.J.F., Gonçalves N.P.F., Burrows H.D., Sarakha M., Fernandes A., Ribeiro M.F., Azenha M.E., Pereira M.M.: Zinc(II) phthalocyanines immobilized in mesoporous silica Al-MCM-41 and their applications in photocatalytic degradation of pesticides. Journal of Hazardous Materials 2012, 233-234, 79. <http://dx.doi.org/10.1016/j.jhazmat.2012.06.059>
  • Pereira Mariette M., Abreu Artur R., Goncalves Nuno P. F., Calvete Mário J. F., Simões Ana V. C., Monteiro Carlos J. P., Arnaut Luís G., Eusébio Maria Ermelinda, Canotilho João: An insight into solvent-free diimide porphyrin reduction: a versatile approach for meso-aryl hydroporphyrin synthesis. Green Chem. 2012, 14, 1666. <http://dx.doi.org/10.1039/c2gc35126a>
  • Han Xue, Bourne Richard A., Poliakoff Martyn, George Michael W.: Immobilised photosensitisers for continuous flow reactions of singlet oxygen in supercritical carbon dioxide. Chem Sci 2011, 2, 1059. <http://dx.doi.org/10.1039/c0sc00641f>