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Pure Appl. Chem., 1988, Vol. 60, No. 4, pp. 517-524

http://dx.doi.org/10.1351/pac198860040517

Macrocyclic complexes of the platinum metals

M. Schröder

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  • Grant Gregory J., Talbott Natalie N., Bajic Marko, Mehne Larry F., Holcombe Thomas J., VanDerveer Donald G.: Heteroleptic platinum(II) and palladium(II) complexes with thiacrown and diimine ligands. Polyedron 2012, 31, 89. <http://dx.doi.org/10.1016/j.poly.2011.08.030>
  • Grant Gregory J.: Pnictogen–thiacrown complexes with Pt(ii) and Pd(ii). Dalton Trans. 2012, 41, 8745. <http://dx.doi.org/10.1039/c2dt30747b>
  • Kabay Nilgün, Gök Yaşar: Synthesis and characterization of new metal-free and metallophthalocyanines containing macrobicyclic moieties. J Inorg Chem Commun 2011, 14, 1880. <http://dx.doi.org/10.1016/j.inoche.2011.08.028>
  • Stoddart J. Fraser, Zarzycki Ryszard: Cyclodextrins as second-sphere ligands for transition metal complexes. Recl Trav Chim Pays-Bas 2010, 107, 515. <http://dx.doi.org/10.1002/recl.19881070902>
  • Edema Jilles J. H., Hoogenraad Marcel, Schoonbeek Franck S., Kellogg Richard M., Kooijman Huub, Spek Anthony L.: Alkylation of the SCS linkage. Towards lipophilic mono- and ditopic heavy-metal receptors containing trithiane building blocks. Molecular structure of cis-2,4,6-tribenzyl-1,3,5-trithiane. Recl Trav Chim Pays-Bas 2010, 112, 370. <http://dx.doi.org/10.1002/recl.19931120611>
  • Shin Richard Y. C., Goh Chun Lian, Goh Lai Yoong, Webster Richard D., Li Yongxin: A Cyclometallated (Azobenzene)palladium(II) Complex of 1,4,7-Trithiacyclononane: Synthesis and Reactivity with Thioether-Dithiolate Metalloligands, Single-Crystal X-ray Diffraction Analyses and Electrochemical Studies. Eur J Inorg Chem 2009, 2009, 2282. <http://dx.doi.org/10.1002/ejic.200900049>
  • González-Calera Silvia, Eisler Dana J., Morey James V., McPartlin Mary, Singh Sanjay, Wright Dominic S.: The Selenium-Based Hexameric Macrocycle [(Se)P(μ-NtBu)2P(μ-Se)]6. Angew Chem 2008, 120, 1127. <http://dx.doi.org/10.1002/ange.200703981>
  • González-Calera Silvia, Eisler Dana J., Morey James V., McPartlin Mary, Singh Sanjay, Wright Dominic S.: The Selenium-Based Hexameric Macrocycle [(Se)P(μ-NtBu)2P(μ-Se)]6. Angew Chem Int Ed 2008, 47, 1111. <http://dx.doi.org/10.1002/anie.200703981>
  • Gott Andrew L., McGowan Patrick C., Podesta Thomas J.: Controlling the binding of dihydrogen using ruthenium complexes containing N-mono-functionalised 1,4,7-triazacyclononane ligand systems. Dalton Trans 2008, 3729. <http://dx.doi.org/10.1039/b804572k>
  • Abramson Sarah, Berkovich-Berger Dvora, Dagan Shai, Goldberg Israel, Golender Lara, Grabarnik Mikhail, Lemcoff N. Gabriel, Weinman Sarah, Fuchs Benzion: Polythiacrown Macro- and Gigantocycles with Chiral Diacetal Cores. Eur J Org Chem 2007, 2007, 1957. <http://dx.doi.org/10.1002/ejoc.200601045>
  • Grant Gregory J., Biggers Desirée A., Vanderveer Donald G.: Contrasting arsine and phosphine coordination behaviour: heteroleptic palladium(II) complexes with triphenylarsine and a crown thioether. Main Group Chem 2007, 6, 249. <http://dx.doi.org/10.1080/10241220801927767>
  • Grant Gregory J., Chen Weinan, Goforth Andrea M., Baucom Clarilyn L., Patel Ketankumar, Repovic Pavle, VanDerveer Donald G., Pennington William T.: Anion and Solvent Effects upon the Structures of Platinum(II) Complexes with Thiacrown Ligands: The Crystal Structures of [Pt(9S3)2](PF6)2·2 CH3NO2, [Pt(9S3)2](BF4)2·2 CH3NO2, [Pt(9S3)2](OTf)2·2 CH3NO2, and [Pt(18S6)](BF4)2. Eur J Inorg Chem 2005, 2005, 479. <http://dx.doi.org/10.1002/ejic.200400461>
  • Iengo Elisabetta, Zangrando Ennio, Baiutti Edi, Munini Fabio, Alessio Enzo: Synthesis and Structural and Spectroscopic Characterization of New RuII-dmso Precursors with Face-Capping Ligands for Use in Self-Assembly Reactions. Eur J Inorg Chem 2005, 2005, 1019. <http://dx.doi.org/10.1002/ejic.200400717>
  • Serli Barbara, Zangrando Ennio, Gianferrara Teresa, Scolaro Claudine, Dyson Paul J., Bergamo Alberta, Alessio Enzo: Is the Aromatic Fragment of Piano-Stool Ruthenium Compounds an Essential Feature for Anticancer Activity? The Development of New RuII-[9]aneS3 Analogues. Eur J Inorg Chem 2005, 2005, 3423. <http://dx.doi.org/10.1002/ejic.200500210>
  • Grant Gregory J., Goforth Andrea M., VanDerveer Donald G., Pennington William T.: Homoleptic platinum(II) and palladium(II) complexes of 1,5,9-trithiacyclododecane: the crystal structures of [Pt(12S3)2](PF6)2·2CH3NO2 and [Pd(12S3)2](BF4)2·0.5H2O. Inorg Chim Ada 2004, 357, 2107. <http://dx.doi.org/10.1016/j.ica.2003.10.033>
  • Lai Yee-Hing, Mok Kum Fun, Vetrichelvan Muthalagu: Synthesis, characterization and crystal structures of Cu(II) and Pd(II) complexes of the pentadentate mixed donor macrocycle, [17]aneNO2S2. Inorg Chim Ada 2004, 357, 1397. <http://dx.doi.org/10.1016/j.ica.2003.11.004>
  • Grant Gregory J., Patel Ketankumar N., Helm Monte L., Mehne Larry F., Klinger David W., VanDerveer Donald G.: Heteroleptic platinum(II) complexes with crown thioethers and diimine ligands: the crystal structures of [Pt(9S3)(2,2′-bipy)](PF6)2 and [Pt(9S3)(4,4-dimethyl-2,2′-bipy)](PF6)2·2.5CH3NO2. J Polyhedron 2004, 23, 1361. <http://dx.doi.org/10.1016/j.poly.2004.02.023>
  • Grant Gregory J., Pool Jaime A., VanDerveer Donald G.: Chiral effects on a fluxional ligand: chiral diphosphine platinum(ii) complexes with thiacrowns. Dalton Trans 2003, 3981. <http://dx.doi.org/10.1039/b306663k>
  • Helm Monte L, Combs Charles M, VanDerveer Donald G, Grant Gregory J: Homoleptic Group 12 metal complexes of macrocyclic thioethers: the crystal structures of bis(1,4,7-trithiacyclodecane)M(II) perchlorate: M(II)=zinc(II), cadmium(II), mercury(II). Inorg Chim Ada 2002, 338, 182. <http://dx.doi.org/10.1016/S0020-1693(02)01016-2>
  • Grant Gregory J., Galas David F., VanDerveer Donald G.: Heteroleptic platinum(II) complexes with crown thioether and phosphine ligands: the crystal structures of [Pt(9S3)(PPh3)Cl](PF6)·CH3NO2 and [Pt(10S3)(PPh3)Cl](PF6). J Polyhedron 2002, 21, 879. <http://dx.doi.org/10.1016/S0277-5387(02)00870-7>
  • Grant Gregory J., Brandow Christopher G., Bruce Chrystal Williams, Bryant Mark A., Kirk Rebecca M., Lee Sabrina D., Rickerd Kerry R., Mehne Larry F.: Metal binding studies with macrocyclic hexathioethers: Transition metal complexes of 22S6 and 20S6. J Heterocyclic Chem 2001, 38, 1281. <http://dx.doi.org/10.1002/jhet.5570380607>
  • Grant Gregory J, Shoup Shara S, Baucom Clairalyn L, Setzer William N: Complexation and conformational analysis studies of 11-membered ring crown trithioethers. Inorg Chim Ada 2001, 317, 91. <http://dx.doi.org/10.1016/S0020-1693(01)00341-3>
  • Grant Gregory J, Carter Shawn M, LeBron Russell A, Poullaos Ivan M, VanDerveer Donald G: Synthetic, electrochemical, and structural studies on heterobimetallic crown thioether complexes with Group 10 metals: the crystal structures of [Pt(9S3)(dppf)](PF6)2·CH3NO2 and [Pd(9S3)(dppf)](PF6)2·CH3NO2. J Organomet Chem 2001, 637-639, 683. <http://dx.doi.org/10.1016/S0022-328X(01)00964-0>
  • Grant Gregory J, Brandow Christopher G, Galas David F, Davis Jaime P, Pennington William T, Valente Edward J, Zubkowski Jeffrey D: Heteroleptic platinum(II) complexes of macrocyclic thioethers and halides: the crystal structures of [Pt(9S3)Cl2], [Pt(9S3)Br2], and [Pt(9S3)I2]. J Polyhedron 2001, 20, 3333. <http://dx.doi.org/10.1016/S0277-5387(01)00953-6>
  • Grant Gregory J, Jones Myron W, Loveday Kristi D, VanDerveer Donald G, Pennington William T, Eagle Cassandra T, Mehne Larry F: Transition metal complexes with macrocyclic oxathiaethers. Inorg Chim Ada 2000, 300-302, 250. <http://dx.doi.org/10.1016/S0020-1693(99)00602-7>
  • Grant Gregory J, Salupo-Bryant Terese, Holt Lisa A, Morrissey Denise Y, Gray Mary Jo, Zubkowski Jeffrey D, Valente Edward J, Mehne Larry F: Synthesis and X-ray crystal structures of mixed sandwich Group 8 cyclopentadienyl complexes containing crown trithioether ligands. J Organomet Chem 1999, 587, 207. <http://dx.doi.org/10.1016/S0022-328X(99)00322-8>
  • Bett J.S., Kunz H.R., Aldykiewicz A.J., Fenton J.M., Bailey W.F., McGrath D.V.: Platinum-macrocycle co-catalysts for the electrochemical oxidation of methanol. Electrochimica Acta 1998, 43, 3645. <http://dx.doi.org/10.1016/S0013-4686(98)00122-4>
  • Hadden Chad E., VanDerveer Donald G., Grant Gregory J., Shoup Shara S.: Cobalt(III) complexes of crown thioethers: the crystal structure of (1,4,7,11,14,17-hexathiacycloeicosane) cobalt (III) tetrafluoroborate dihydrate. Inorg Chim Ada 1998, 274, 192. <http://dx.doi.org/10.1016/S0020-1693(97)06054-4>
  • Grant Gregory J., McCosar Bruce M., Setzer William N., Zubkowski Jeffrey D., Valente Edward J., Mehne Larry F.: The synthesis and structure of bis(1,4,7-trithiacyclodecane)-ruthenium (II) perchlorate: the meso diastereoisomer. Inorg Chim Ada 1996, 244, 73. <http://dx.doi.org/10.1016/0020-1693(95)04752-2>
  • Grant Gregory J., Spangler Nathan J., Setzer William N., VanDerveer Donald G., Mehne Larry F.: Synthesis and complexation studies of mesocyclic and macrocyclic polythioethers XIV. Crown thioether complexes of palladium(II) and platinum(II). Inorg Chim Ada 1996, 246, 31. <http://dx.doi.org/10.1016/0020-1693(96)05047-5>
  • Jenkins Hilary A., Loeb Stephen J., Riera Antoni Malats i.: Tetranuclear Ag(I) complexes with an octagonal Ag4S4 core: building large structures from small macrocycles. Inorg Chim Ada 1996, 246, 207. <http://dx.doi.org/10.1016/0020-1693(96)05067-0>
  • A. Bennett Martin, C. Willis Anthony, Yoong Goh Lai, Chen Wei: Divalent ruthenium complexes containing 1,4,7-trithiacyclononane and cycloocta-1,5-diene (C8H12) or 1–3:5,6η-Cyclooctadienyl (C8H11). J Polyhedron 1996, 15, 3559. <http://dx.doi.org/10.1016/0277-5387(96)00073-3>
  • Grant Gregory J., Rogers Karen E., Setzer William N., VanDerveer Donald G.: Crown thioether complexes of trivalent transition metal ions. The crystal structure of [Cr(18S6)Cl3]. Inorg Chim Ada 1995, 234, 35. <http://dx.doi.org/10.1016/0020-1693(95)04462-I>
  • Guyon V., Guy A., Foos J., Lemaire M., Draye M.: Lipophilic polythiamacrocycles as palladium extracting agents. Tetrahedron 1995, 51, 4065. <http://dx.doi.org/10.1016/0040-4020(95)00147-Z>
  • Ingham Scott L., Long Nicholas J.: Der erste Metallkomplex mit einem doppelt S3-verbrückten Ferrocen als Liganden. Angew Chem 1994, 106, 1847. <http://dx.doi.org/10.1002/ange.19941061725>
  • Blake Alexander J., Reid Gillain, Schröder Martin: Platinum metal complexes of hexa-aza macrocycles: Synthesis and single crystal X-ray structure of [Pd2Cl2(Me6[18]aneN6)](PF6)2 (Me6[18]aneN6  1,4,7,10,13,16-hexamethyl-1,4,7,10,13,16-hexaazacyclooctadecane). J Polyhedron 1994, 13, 2135. <http://dx.doi.org/10.1016/S0277-5387(00)81494-1>
  • Cristiani Franco, Devillanova Francesco A., Isaia Francesco, Lippolis Vito, Verani Gaetano, Demartin Francesco: Spectroscopic studies and X-ray crystal structures of charge-transfer complexes of 1,4,7-trithiacyclononane with diiodine. Heteroatom Chem 1993, 4, 571. <http://dx.doi.org/10.1002/hc.520040609>
  • Edema Jilles J.H, Stock H.Thijs, Buter Jan, Kellogg Richard M, Smeets Wilberth J.J, Spek Anthony L: Boric acid mediated preparation of mesocyclic thiocrown ethers containing xylylene units. Molecular structures of 3,8-dibenzo-1,6-di-thiacyclodecane and 2,5,8-trithia-(9)-p-benzenophane. Tetrahedron 1993, 49, 4355. <http://dx.doi.org/10.1016/S0040-4020(01)85752-5>
  • Suh Il-Hwan, Weber Edwin, Reutel Christiane, Sobhia Masilamani E., Panneerselvam Kaliyamoorthy, Chacko Kizakkekoikkal K.: Crystal structure of the 2:1 complex of mercury(II) chloride with trithiapyridino-12-crown-4 having unusual mercury coordination. Inorg Chim Ada 1992, 194, 93. <http://dx.doi.org/10.1016/S0020-1693(00)85828-4>
  • Blake Alexander J., Reid Gillian, Schröder Martin: Thioether macrocyclic chemistry: Synthesis of [RhCl([15]aneS5)]2+ and [Ru(PPh3)([15]aneS5)]2+. The single crystal X-ray structure of [Ru(PPh3)([15]aneS5)](BPh4)2 ([15]aneS5 = 1,4,7,10,13-pentathiacyclopentadecane). J Polyhedron 1992, 11, 2501. <http://dx.doi.org/10.1016/S0277-5387(00)83570-6>
  • Collison David, Reid Gillian, Schröder Martin: Rhodium thioether chemistry: the synthesis and electrochemistry of [Rh([18]aneS6)]3+ and the ring-opened vinyl thioether complexes [Rh([18]aneS6-H)]2+ and [Rh(Me2[18]aneN2S4-H)]2+ ([18]aneS6 = 1,4,7,10,13,16-hexathiacyclooctadecane, Me2[18]aneN2S4 = 1,10-dimethyl-1,10-diaza-4,7,13,16-tetrathiacyclooctadecane). J Polyhedron 1992, 11, 3165. <http://dx.doi.org/10.1016/S0277-5387(00)83659-1>
  • Edema Jilles J.H., Buter Jan, Kellogg Richard M.: Synthesis of the macrocyclic thiocrown ethers 1,4,7,10,13,16,19-heptathiaheneicosane (21-S-7) and 1,4,7,10,13,16,19,22-octathiatetraeicosane (24-S-8). Tetrahedron 1991, 50, 2095. <http://dx.doi.org/10.1016/S0040-4020(01)85071-7>
  • Ludwig R., Fischer S., Dreyer R., Jacobi R., Beger J.: Complex formation equilibria between astatine(I) and sulphur-containing chelating ligands. J Polyhedron 1991, 10, 11. <http://dx.doi.org/10.1016/S0277-5387(00)83540-8>
  • Blake Alexander J., Pasteur Elizabeth C., Reid Gillian, Schröder Martin: Mercury thioether chemistry: The synthesis and X-ray crystal structure of [Hg([15]aneS5](PF6)2. J Polyhedron 1991, 10, 1545. <http://dx.doi.org/10.1016/S0277-5387(00)86078-7>
  • Blake Alexander J., Greig John A., Holder Alan J., Hyde Timothy I., Taylor Anne, Schröder Martin: Bis(1,4,7-trithiacyclononan)gold-Dikation: Ein paramagnetischer, einkerniger AuII-Komplex. Angew Chem 1990, 102, 203. <http://dx.doi.org/10.1002/ange.19901020216>
  • Blake Alexander J., Gould Robert O., Holder Alan J., Lavery Aidan J., Schröder Martin: Copper thioether chemistry: The synthesis and single crystal X-ray structures of [Cu2([18]aneS6)(NCMe)2](ClO4)2 and [Cu([9]aneS3)(AsPPh3)](ClO4). J Polyhedron 1990, 9, 2919. <http://dx.doi.org/10.1016/S0277-5387(00)84201-1>
  • Blake Alexander J., Reid Gillian, Schröder Martin: Rhodium macrocyclic complexes: The synthesis and single crystal X-ray structure of [Rh([18]aneN2S4)](PF6)3 · 3H2O ([18]aneN2S4 = 1,4,10,13-tetrathia-7,16-diazacyclooctadecane). J Polyhedron 1990, 9, 2925. <http://dx.doi.org/10.1016/S0277-5387(00)84202-3>
  • Küppers H.-J., Wieghardt K., Nuber B., Weiss J.: Kronenthioetherkomplexe des Blei(II), Zink(II) und Cadmium (II) und Cadmium(II). Die Kristallstrukturen von [PbL2(ClO4)2] und [ZnL2](ClO4)2 · CH3CN (L = 1,4,7 - Trithiacyclononan). Z anorg allg Chem 1989, 577, 155. <http://dx.doi.org/10.1002/zaac.19895770117>
  • Blake Alexander J., Crofts Rhona D., Reid Gillian, Schröder Martin: Organometallic macrocyclic complexes: the synthesis, electrochemistry and single crystal X-ray structure of [Fe(C5H5)(L)]+ (L = 1,4,7-trithiacyclononane). J Organomet Chem 1989, 359, 371. <http://dx.doi.org/10.1016/0022-328X(89)88098-2>
  • Blake Alexander J., Holder Alan J., Hyde Timothy I., Reid Gillian, Schröder Martin: Mercury thioether chemistry: The synthesis and structure of [Hg([9]aneS3)2](PF6)2 ([9]aneS3 = 1,4,7-trithiacyclononane). J Polyhedron 1989, 8, 2041. <http://dx.doi.org/10.1016/S0277-5387(00)80501-X>
  • Blake Alexander J., Gould Robert O., Holder Alan J., Hyde Timothy I., Schröder Martin: Silver thioether chemistry: Synthesis, X-ray crystal structure and redox properties of [Ag([18]aneS6)]+ ([18]aneS6 = 1,4,7,10,13,16-hexathiacyclooctadecane). J Polyhedron 1989, 8, 513. <http://dx.doi.org/10.1016/S0277-5387(00)80749-4>
  • Parker David, Craig Andrew S., Ferguson George, Lough Alan J.: Preparation and X-ray crystal structure of a silver sandwich complex of an aza-thia macrocycle. J Polyhedron 1989, 8, 2951. <http://dx.doi.org/10.1016/S0277-5387(00)86298-1>
  • Blake Alexander J., Gould Robert O., Reid Gillian, Schröder Martin: Platinum metal thioether macrocyclic complexes: synthesis and single crystal X-ray structure of cis-[IrCl2(L)]BPh4 (L = 1,4,8,11-tetrathiacyclotetradecane). J Organomet Chem 1988, 356, 389. <http://dx.doi.org/10.1016/0022-328X(88)83155-3>